![]() The synthesis of 5-nitro-1,10-phenanthroline hydrate 2 derivatives from 1,10-phenanthroline monohydrate as starting material has been carried out. Its means that there were only a relatively few deviations between the experimental and theoretical data of antimalarial activity The equation was significant on the 95 % level with statistical parameters: n = 15 r = 0.951 r2 = 0.905 SE = 1.326498 Fcalc/Ftable = 1.029 and gave the PRESS = 5.650972. Antiplasmodial activities were taken as the activity of the drugs against chloroquine-resistant plasmodiumfalciparum FCR3 strain and are presented as the value of ln (1/IC50) where IC50 is an effective concentration inhibiting 50 % of the parasite growth. The descriptors were obtained from computational chemistry method using semi-empirical PM3. Quantitative electronic structure-activity relationship (QSAR) analysis of a series of mangostin derivatives as antiplasmodial compounds have been conducted using atomic net charges (q), dipole moment (µ) ELUMO, EHOMO, polarizability (α), log P and massa molecular as the descriptors. Kekerasan yang tinggi dan kestabilan intan disebabkan oleh peleburan atom-atom ke dalam cincin sikloheksana dalam jumlah tak terhingga dan semuanya dalam bentuk kursi yang stabil. Kalau senyawa tersebut dimodifikasi lebih lanjut dengan memadukan cincin dengan enam atom ke segala arah sehingga semua atom hidrogennya terganti oleh karbon dari cincin tersebut sehingga diperoleh karbon murni, intan. Senyawa kongresan yang berbentuk sangkar telah disintesis oleh seorang kimiawan yang kemudian mendapat penghargaan dari IUPAC pada tahun 1963. Cincin dengan enam atom karbon dengan konformasi kursi dapat terpadu secara sempurna dan terjalin tanpa tegangan. Tiga buah cincin sikloheksana dan sebuah cincin siklopentana dapat terpadu membentuk 1,2-siklopentanoperhidrofenantren yang merupakan kerangka dasar dari senyawa steroid dan berbagai hormon (akan dibahas pada bab berikutnya). Tiga buah cincin sikloheksana yang terpadu dapat berada dalam bentuk cis dan trans. Dekalin mengandung dua cincin sikloheksana yang terpadu, dapat berada dalam bentuk cis dan trans. Cincin-cincin terpadupun dapat mengalami tekukan untuk mencapai keadaan yang lebih mantap. Gambar 3.30 Beberapa hidrokarbon siklik cincin terpadu 3.7.1 Konformasi cincin-cincin terpadu Mengacu pada azas kestabilan struktur molekul, sebagaimana telah dibahas pada struktur konformasi sikloheksan. ![]()
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Firefox extensions enable users to customize Firefox with additional features. ![]() |
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